AIP Advances (Apr 2018)

Thermally stimulated depolarization current study on barium titanate single crystals

  • Wanghua Wu,
  • Zhifu Liu,
  • Yan Gu,
  • Zhenxing Yue,
  • Yongxiang Li

DOI
https://doi.org/10.1063/1.5025501
Journal volume & issue
Vol. 8, no. 4
pp. 045005 – 045005-6

Abstract

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Thermally stimulated depolarization current (TSDC) measurements were applied to investigate BaTiO3 single crystals with , , and orientations, and annealed under different atmospheres, respectively. The TSDC peaks related to ferroelectric domain, ferroelectric–paraelectric phase transition, TiTi′−VÖ dipole relaxation and oxygen vacancy migration were observed from the TSDC spectra. The formation of oxygen vacancy clusters in BaTiO3 single crystals leads to a high dipole activation energy. The crystalline face of BaTiO3 is more stable under external field than others.