Hierarchical Nanostructures of Iron Phthalocyanine Nanowires Coated on Nickel Foam as Catalysts for the Oxygen Evolution Reaction

Abstract

In this paper, iron phthalocyanine nanowires on a nickel foam (FePc@NF) composite catalyst were prepared by a facile solvothermal approach. The catalyst showed good electrochemical oxygen evolution performance. In 1.0 M KOH electrolyte, 289 mV low overpotential and 49.9 mV dec−1 Tafel slope were seen at a current density of 10 mA cm−2. The excellent electrochemical performance comes from the homogeneous dispersion of phthalocyanine nanostructures on the surface of the nickel foam, which avoids the common agglomeration problem of such catalysts and provides a large number of active sites for the OER reaction, thus improving the catalytic performance of the system.

Keywords

• electrocatalysis
• phthalocyanine
• OER
• solvothermal