Acta Crystallographica Section E (Jul 2009)
2-(1,2,3,4-Tetrahydrophenanthren-1-ylidene)malononitrile
Abstract
In the title complex, C17H12N2, the non-aromatic six-membered ring adopts an envelope conformation. The dihedral angle between the eight-membered plane containing the malononitrile group and the aromatic system is 25.88 (4)°. The distance from the central C atom of the malononitrile group to the centroid of the n-glide-related distal aromatic ring is 3.66 Å, suggesting π–π interactions.