Acta Crystallographica Section E (Jul 2009)

2-(1,2,3,4-Tetrahydrophenanthren-1-ylidene)malononitrile

  • George B. Ettenger,
  • Brian Wesley Williams,
  • Daniel Brillhart,
  • Margaret E. Kastner

DOI
https://doi.org/10.1107/S1600536809023988
Journal volume & issue
Vol. 65, no. 7
pp. o1711 – o1711

Abstract

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In the title complex, C17H12N2, the non-aromatic six-membered ring adopts an envelope conformation. The dihedral angle between the eight-membered plane containing the malononitrile group and the aromatic system is 25.88 (4)°. The distance from the central C atom of the malononitrile group to the centroid of the n-glide-related distal aromatic ring is 3.66 Å, suggesting π–π interactions.