Enantioselective construction of six- and seven-membered triorgano-substituted silicon-stereogenic heterocycles

Abstract

Enantioenriched medium-sized silicon-stereogenic heterocycles are in high demand due to the potential use in functional materials. Here, the authors show a rhodium-catalyzed enantioselective synthesis of six- and seven-membered tri-organosubstituted silicon-stereogenic heterocycles.