Adsorption Science & Technology (Feb 2007)

Adsorption and Complexing Properties of Silicas with Analytical Reagents Grafted via the Mannich Reaction

  • E.S. Yanovska,
  • V.A. Tertykh,
  • O.Yu. Kichkiruk,
  • A.D. Dadashev

DOI
https://doi.org/10.1260/026361707781485726
Journal volume & issue
Vol. 25

Abstract

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The pre-concentration of metal ions such as Pb(II), Cd(II), Zn(II), Hg(II) and Mo(VI) on silicas with covalently bound 8-hydroxyquinoline, 1-(2-pyridylazo)-2-naphthol or 4-(2-pyridylazo)resorcinol has been studied. The structures of metal-ion complexes with grafted phenolic-type analytical reagents were investigated by IR, ESR and electronic diffuse reflectance spectroscopies.