Kinetics of Low-Grade Scheelite Leaching with a Mixture of Sodium Phosphate and Sodium Fluoride

Abstract

The current technology of leaching low-grade scheelite with sodium hydroxide or sodium carbonate has the disadvantages of large leaching reagent dosage and low leaching efficiency of tungsten. In order to extract scheelite efficiently, the kinetics of low-grade scheelite leaching with a mixture of sodium phosphate and sodium fluoride was investigated. In this study, the effects of temperature, phosphate concentration, and fluoride ion concentration on the leaching rate of tungsten were investigated. Our results showed that the leaching rate of tungsten was greatly influenced by the temperature and less affected by the concentration of phosphate and fluorine ions. The leaching process was controlled by a chemical reaction with an apparent activation energy value of 51 ± 0.2 kJ/mol. The apparent reaction orders with respect to phosphate and fluorine ions were 0.49 and 0.11, respectively. The reaction product calcium fluorophosphate was a loose, rod-like crystal, which would not tightly wrap on the surface of scheelite to prevent the diffusion process. The leaching kinetics of low-grade scheelite was in accordance with the shrinking core model, and the corresponding kinetic equation was also established.

Keywords

• scheelite
• sodium phosphate
• calcium fluoride
• calcium fluorophosphate
• leaching kinetics