Nature Communications (Jun 2020)

Synthesis and versatile reactivity of scandium phosphinophosphinidene complexes

  • Bin Feng,
  • Li Xiang,
  • Karl N. McCabe,
  • Laurent Maron,
  • Xuebing Leng,
  • Yaofeng Chen

DOI
https://doi.org/10.1038/s41467-020-16773-w
Journal volume & issue
Vol. 11, no. 1
pp. 1 – 8

Abstract

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Rare-earth monometallic phosphinidene complexes have been elusive synthetic targets. Here, the authors describe the synthesis and tunable reactivity of two scandium phosphinophosphinidene complexes containing very unusual Sc-P multiple bonds.