Advancing Thermochromic Glass Durability: Reinforcing Thermosensitive Hydrogels with Enhanced Adhesion Techniques

Abstract

The growing use of glass in architecture has driven research into reducing its energy consumption. Thermochromic (TC) glass technology shows promise for enhancing building energy efficiency by regulating solar heat dynamically. Although TC glass helps reduce heat radiation, additional solutions like Low-E or vacuum glass are needed to control heat convection and conduction. Low-E glass, while effective in lowering heat transfer, may increase surface temperature. Thermo-sensitive hydrogels, known for their light-scattering properties at high temperatures, have been explored to complement TC glass. However, their stability at elevated temperatures remains a challenge, especially for applications requiring durability under varying weather conditions. This study proposes enhancing the adhesion between hydrogel and glass by introducing silica–oxygen bonds. As a result, TC glass demonstrates stable performance over 100 cycles within temperature ranges from 85 °C to 30 °C in summer and 40 °C to −20 °C in winter. Furthermore, by incorporating ethylene glycol, the freezing point of TC glass is reduced to −26 °C, rendering it suitable for use in colder regions. The implementation of TC glass effectively addresses the dual requirements of summer shading and winter heating in areas with both cold winters and hot summers, significantly reducing building energy consumption. This study contributes substantially to developing advanced intelligent building materials, paving the way for more sustainable architectural designs.

Keywords

• thermochromic glass
• hydrogel
• silica–oxygen bonds
• LCST