New Homometallic Octanuclear Chromium(III) Rings

Abstract

Four new {Cr8} rings have been synthesized and characterized; they are all based on the classic [CrF(O2CtBu)2]8 ring 1. Three routes have been studied. The first is direct synthesis, by reacting hydrated chromium(III) fluorides with the acid; this has been used to produce LS[CrF(O2CEt)2]8 3. The second route uses 3 as a precursor and substitute with an incoming carboxylate. This has been used to make [CrF(O2CCCl3)2]8 4 and [CrF(O2CC6F5)2]8 5. The third route uses LSN-ethyl-D-glucamine (H5Etglu) as a template and produces chiral rings [Cr8F4(Etglu)(O2CtBu)15] 6. The single crystal X-ray structures of these new compounds are reported.

Keywords

• chromium
• carboxylate
• polymetallic ring
• crystallography