Copper oxide nanoparticles doped with lanthanum, magnesium and manganese: optical and structural characterization

Abstract

Copper oxide (Cu2O) is a promising semiconductor for photovoltaic and photocatalytic applications since this material has a high optical absorption coefficient and lower band gap (2.17 eV). Doped lanthanum (La), magnesium (Mg) and manganese (Mn) Cu2O nanoparticles (Cu2O Nps) were prepared by a displacement reaction. The doped and undoped Cu2O Nps were characterized with scanning electron microscopy–energy dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), transmission electron microscopy (TEM) and ultraviolet–visible spectroscopy. The EDS results confirm the presence of La, Mg and Mn in the Cu2O Nps. The XRD results confirm the formation a single cubic phase of Cu2O with a cuprite structure. TEM images confirm the formation of Nps with mean diameters between 12.0 ± 6.1 and 30.8 ± 11.0 nm. Doped and undoped Nps present a narrow band gap (2.40 eV), blue shifted with respect to bulk Cu2O.

Keywords

• cuprous oxide nanoparticles
• band gap
• lanthanum
• magnesium
• manganese