Nature Communications (Oct 2016)

Heme biomolecule as redox mediator and oxygen shuttle for efficient charging of lithium-oxygen batteries

  • Won-Hee Ryu,
  • Forrest S. Gittleson,
  • Julianne M. Thomsen,
  • Jinyang Li,
  • Mark J. Schwab,
  • Gary W. Brudvig,
  • André D. Taylor

DOI
https://doi.org/10.1038/ncomms12925
Journal volume & issue
Vol. 7, no. 1
pp. 1 – 10

Abstract

Read online

Natural biomolecules including heme-like porphyrins can be applied as sustainable chemical catalysts in lithium-oxygen batteries. Here, the authors show that the heme molecule can function as a soluble redox catalyst and oxygen shuttle for efficient oxygen evolution in non-aqueous lithium-oxygen cells.