Novel Process for Carbon Cycle Utilization from Industrial Flue Gas into Methanol

Abstract

Reduction of greenhouse gas (GHG) emissions for mitigating climate changes is globally necessary. As a major GHG emitter, refinery sector is responsible for 14.1% of China’s CO2 emission in 2019. The flue gas associated with petroleum refining has high CO2 content, presenting potentials for methanol and electricity co-production when the methane and hydrogen in dry gas are considered. To unlock the green opportunity for refineries, in this study we employed Aspen Plus to develop the process of methanol synthesis by recovering CO2 in the flue gas of fluid catalytic cracking (FCC) unit and the methane and hydrogen in dry gas. The results show that the new co-production process increases the energy efficiency of the FCC unit by 2.4%. Compared with traditionally natural gas-based methanol production, the developed process enables annual CO2 mitigation of 1.3 million tons.