Structure, Luminescence and Temperature Detection Capability of [C(NH₂)₃]M(HCOO)₃ (M = Mg²⁺, Mn²⁺, Zn²⁺) Hybrid Organic–Inorganic Formate Perovskites Containing Cr³⁺ Ions

Abstract

Metal-organic frameworks are of great interest to scientists from various fields. This group also includes organic–inorganic hybrids with a perovskite structure. Recently their structural, phonon, and luminescent properties have been paid much attention. However, a new way of characterization of these materials has become luminescence thermometry. Herein, we report the structure, luminescence, and temperature detection ability of formate organic–inorganic perovskite [C(NH2)3]M(HCOO)3 (Mg2+, Mn2+, Zn2+) doped with Cr3+ ions. Crystal field strength (Dq/B) and Racah parameters were determined based on diffuse reflectance spectra. It was shown that Cr3+ ions are positioned in the intermediate crystal field or close to it with a Dq/B range of 2.29–2.41. The co-existence of the spin-forbidden and spin-allowed transitions of Cr3+ ions enable the proposal of an approach for remote readout of the temperature. The relative sensitivity (Sr) can be easily modified by sample composition and Cr3+ ions concentration. The luminescent thermometer based on the 2E/4T2g transitions has the relative sensitivity Sr of 2.08%K−1 at 90 K for [C(NH2)3]Mg(HCOO)3: 1% Cr3+ and decrease to 1.20%K−1 at 100 K and 1.08%K−1 at 90 K for Mn2+ and Zn2+ analogs, respectively.

Keywords

• MOF
• hybrid perovskite
• luminescence
• thermometry
• chromium(III) ions
• temperature sensing