Factors Controlling Hydrothermal Nickel and Cobalt Mineralization—Some Suggestions from Historical Ore Deposits in Italy

Abstract

We compare three poorly known, historical Ni−Co-bearing hydrothermal deposits in different geological settings in Italy: The Ni−Co−As−Sb−Au-bearing Arburese vein system (SW Sardinia), the Co−Ni−As-rich Usseglio vein system (Piedmont), and the small Cu−Ag−Co−Ni−Pb−Te−Se stockwork at Piazza (Liguria). These deposits share various (mineralogical, chemical, thermal, and stable isotopic) similarities to the Five Element Vein-type ores but only the first two were economic for Co−Ni. The Sardinian Ni-rich veins occur in Paleozoic basement near two Variscan plutons. Like the Co-rich Usseglio vein system, the uneconomic Piazza deposit is hosted in an ophiolite setting anomalous for Co. The Sardinian and Usseglio deposits share a polyphasic assemblage with Ni−Co−As−Sb−Bi followed by Ag-base metal sulfides, in siderite-rich gangue, whereas Piazza shows As-free, Ag−Pb−Te−Se-bearing Co−Ni−Cu sulfides, in prehnite−chlorite gangue. Fluid inclusions indicated Co−Ni arsenide precipitation at ≈170 °C for Usseglio, whereas for the Sardinian system late sulfide deposition occurred within the 52−126 °C range. Ore fluids in both systems are NaCl-CaCl2-bearing basinal brines. The chlorite geothermometer at Piazza provides the range of 200−280 °C for ore deposition from CO2-poor fluids. Enrichments in Se and negative δ13C in carbonates suggest interaction with carbonaceous shales. These deposits involve issues about source rocks, controls on Co/Ni and possible role of arsenic and carbonate components towards economic mineralization.

Keywords

• Ni–Co arsenides
• five element vein-type deposits
• fluid inclusions
• basinal brines
• carbonates
• chlorite geothermometer