Removal of As(V) from aqueous solutions using calcium-alginate microspheres with encapsulated iron nanoparticles

Abstract

This work investigated As(V) removal from aqueous solutions using calcium alginate microspheres with encapsulated iron nanoparticles (FeNPs) in batch systems. The kinetic, equilibrium, and thermodynamic parameters of the adsorption process were evaluated. Adsorbents were characterized using Fourier Transform Infrared Spectroscopy, Scanning Electron Microscopy, and Zeta Potential techniques. The FeNPs were obtained by a simple and low-cost method and they were successfully encapsulated and uniformly dispersed over the microspheres' surface. Significantly fast adsorption kinetic rates were observed due to microspheres' particle size and FeNPs encapsulation. The chemisorption mechanism was recognized in both adsorbate-adsorbent systems. The As(V) isotherms data suggested that the process is associated with heterogeneous adsorption. Available sorption sites with different adsorption energies were related to the functional groups involved in removing As(V), such as hydroxyl and carboxyl groups. Significantly high adsorption capacities were obtained for both materials, suggesting they can be competitive compared to conventional adsorbents, even at low FeNPs concentrations. Besides FeNPs encapsulation enhancing arsenate removal, higher adsorption was obtained at slightly acidic pH values and, together with their small particle size, suggests that the microspheres have a great potential to be used as arsenate adsorbents in the water treatment for human consumption. HIGHLIGHTS Iron nanoparticles were successfully prepared and encapsulated using simple methods.; Iron-modified alginate microspheres were highly effective for As(V) removal, particularly at low concentrations.; Fast removal was observed for both arsenate-adsorbent systems.; Significantly high adsorption capacities were obtained for both adsorbents, using low iron nanoparticles concentrations in the microspheres.;

Keywords

• adsorption
• alginate
• arsenic
• iron nanoparticles
• microspheres