Shape-assisted self-assembly

Abstract

Self-assembly and molecular recognition usually depend on strong, directional non-covalent interactions but also topography can play a role in the formation of supramolecular constructs which makes it nearly impossible to discern the potential of shape and motion in the creation of complexity. Here, the authors demonstrate that long-range order in supramolecular constructs can be assisted by the topography of the individual units even in the absence of highly directional interactions.