Crystal structure of bis(μ2-4-bromo-2-[({2-[({2-[(5-bromo-2-oxidobenzylidene)amino]ethyl}sulfanyl)sulfonyl]ethyl}imino)methyl]phenolato)dicopper(II) dimethylformamide disolvate

Abstract

The title dinuclear copper(II) complex [Cu2(C18H16Br2N2O4S2)2] was prepared by direct synthesis of a dianionic Schiff base derived from 5-bromosalicylaldehyde and cysteamine. The discrete molecules lie across inversion centers and crystallize with two dimethylformamide (DMF) molecules of crystallization. The unique CuII ion is four-coordinated by two tetradentate Schiff base ligands in a distorted square-planar N2O2 environment. In the crystal, short intermolecular S...Br contacts, weak C—H...O hydrogen bonds and intra- and intermolecular π–π stacking interactions between rings of the ligand link the components into a two-dimensional network parallel to (010).

Keywords

• crystal structure
• dinuclear copper(II) complex
• Schiff base
• 5-bromosalicylaldehyde
• cysteamine (2-aminoethanthiol)