Acta Crystallographica Section E (May 2009)

Bis(μ-2,2′-bi-1H-imidazole-1,1′-diacetato)bis[diaquacobalt(II)] hexahydrate

  • Hongze Liang,
  • Tingting Zhang,
  • Feng Xu,
  • Tao Zhang

DOI
https://doi.org/10.1107/S1600536809013701
Journal volume & issue
Vol. 65, no. 5
pp. m543 – m544

Abstract

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The dinuclear title compound, [Co2(C10H8N4O4)2(H2O)4]·6H2O, lies about an inversion centre. Each CoII atom is six-coordinated by two water molecules, two carboxylate O atoms and two N atoms of two symmetry-related 2,2′-bi-1H-imidazole-1,1′-diacetate (L2−) ligands in a slightly distorted octahedral geometry. Molecules are linked into a three-dimensional framework via O—H...O and C—H...O hydrogen bonds.