Effect of Cu-Doped Carbon Quantum Dot Dispersion Liquid on the Lubrication Performance of Polyethylene Glycol

Abstract

Energy saving and reduced consumption of key materials such as bearings in high-end equipment can be realized by synthesizing a new lubricating functional additive, copper-doped carbon quantum dot dispersion liquid (Cu-CQDs) via hydrothermal reaction with glycerol, cupric chloride dihydrate, and choline chloride as raw materials. The influence of the dispersion liquid containing Cu-CQDs nanoparticles on the lubricating properties of polyethylene glycol (PEG200) was investigated on a four-ball friction tester. The wear scars of steel balls after friction were analyzed using a scanning electron microscope accompanied by energy dispersive spectroscopy (SEM/EDS), photoelectron microscopy, and Raman spectroscopy. The results revealed the friction and wear mechanism of Cu-CQDs. Cu-CQDs dispersion liquid can significantly enhance the lubrication performance of PEG. The average friction coefficient of PEG containing 2.0 wt% Cu-CQDs dispersion liquid was 40.99% lower than that of pure PEG. The friction and wear mechanism can be ascribed to friction, inducing Cu-CQDs to participate in the formation of boundary lubricating film, resulting in a low friction coefficient and wear scar diameter.

Keywords

• copper doping
• carbon quantum dots
• boundary lubricating film
• friction and wear mechanism