APL Materials (Jun 2015)

Tailoring the electronic transitions of NdNiO3 films through (111)pc oriented interfaces

  • S. Catalano,
  • M. Gibert,
  • V. Bisogni,
  • F. He,
  • R. Sutarto,
  • M. Viret,
  • P. Zubko,
  • R. Scherwitzl,
  • G. A. Sawatzky,
  • T. Schmitt,
  • J.-M. Triscone

DOI
https://doi.org/10.1063/1.4919803
Journal volume & issue
Vol. 3, no. 6
pp. 062506 – 062506-7

Abstract

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Bulk NdNiO3 and thin films grown along the pseudocubic (001)pc axis display a 1st order metal to insulator transition (MIT) together with a Néel transition at T = 200 K. Here, we show that for NdNiO3 films deposited on (111)pc NdGaO3, the MIT occurs at T = 335 K and the Néel transition at T = 230 K. By comparing transport and magnetic properties of layers grown on substrates with different symmetries and lattice parameters, we demonstrate a particularly large tuning when the epitaxy is realized on (111)pc surfaces. We attribute this effect to the specific lattice matching conditions imposed along this direction when using orthorhombic substrates.