Dicarbonylchlorido(phenoxythiocarbonyl-κ2C,S)bis(triphenylphosphane-κP)molybdenum(II)

Abstract

In the title complex, [Mo(C7H5OS)Cl(C18H15P)2(CO)2], the geometry around the metal atom is a capped octahedron. The phenoxythiocarbonyl ligand coordinates the MoII atom through the C and S atoms. A one-dimensional structure is formed by π–π intermolecular interactions and a supramolecular aggregation is determined by intermolecular C—H...O, C—H...Cl, C—H...π(arene) hydrogen bonds and CO...π(arene) interactions [O...centroid distances = 3.485 (4) and 3.722 (3) Å].