Study on Explosion Mechanism of Dimethyl Ether/H₂-Blended Gas Based on Chemical Kinetics Method

Abstract

In order to reveal the deflagration mechanism of DME/H2-blended gasses, the micro-mechanism was studied based on the constructed UC San Diego 2016 pyrolysis oxidation mechanism model. The results show that adiabatic flame temperature and laminar flame speed increase with the increase in the equivalence ratio (Φ); they first increase and then decrease with the increase in the hydrogen (H2)-blended ratio (λ), and with the increase in λ, the Φ corresponding to the peak laminar flame speed of the blended gas increases. The addition of H2 increases the consumption of O2, and H2 reacts with CO to form H2O and CO2, promoting complete combustion. When Φ = 1.0–1.2, the equilibrium mole fraction of H and OH-activated radicals reach the maximum, and with the addition of H2, the concentration of activating radicals gradually increases, while the number of promoted elementary reactions increases by two, and the number of inhibited elementary reactions does not increase. Meanwhile, the addition of H2 increases the reaction rate of most reactions on the main chemical reaction path CH3OCH3→CH3OCH2→CH2O→HCO→CO→CO2 of DME and increases the risk of the deflagration of DME/H2-blended gas.

Keywords

• DME/H₂-blended gas
• pyrolysis oxidation mechanism model
• chemical reaction kinetics
• equivalence ratio
• hydrogen-blended ratio