Facile Synthesis of Sn/Nitrogen-Doped Reduced Graphene Oxide Nanocomposites with Superb Lithium Storage Properties

Abstract

Sn/Nitrogen-doped reduced graphene oxide (Sn@N-G) composites have been successfully synthesized via a facile method for lithium-ion batteries. Compared with the Sn or Sn/graphene anodes, the Sn@N-G anode exhibits a superb rate capability of 535 mAh g−1 at 2C and cycling stability up to 300 cycles at 0.5C. The improved lithium-storage performance of Sn@N-G anode could be ascribed to the effective graphene wrapping, which accommodates the large volume change of Sn during the charge−discharge process, while the nitrogen doping increases the electronic conductivity of graphene, as well as provides a large number of active sites as reservoirs for Li+ storage.

Keywords

• Sn anode
• N doping
• graphene nanocomposites
• rate performance
• lithium-ion batteries