Research on mix design and mechanical performances of MK-GGBFS based geopolymer pastes using central composite design method

Abstract

Abstract In order to alleviate environmental problems and reduce CO2 emissions, geopolymers had drew attention as a kind of alkali-activated materials. Geopolymers are easier access to raw materials, green and environment friendly than traditional cement industry. Its special reaction mechanism and gel structure show excellent characteristics such as quick hardening, high strength, acid and alkali resistance. In this paper, geopolymer pastes were made with metakaolin (MK) and ground granulated blast furnace slag (GGBFS) as precursors. The effects of liquid–solid ratio (L/S) and modulus of sodium silicate (Ms) on the performances of MK-GGBFS based geopolymer paste (MSGP) were characterized by workability, strength and microstructural tests. The regression equations were obtained by central composite design method to optimize the mix design of MSGP. The goodness of fit of all the equations were more than 98%. Based on the results of experiments, the optimum mix design was found to have L/S of 0.75 and Ms of 1.55. The workability of MSGP was significantly improved while maintaining the strength under the optimum mix design. The initial setting time of MSGP decreased by 71.8%, while both of the fluidity and 28-d compressive strength increased by 15.3%, compared with ordinary Portland cement pastes. Therefore, geopolymers are promising alternative cementitious material, which can consume a large amount of MK and GGBFS and promote green and clean production.

Keywords

• Metakaolin
• Slag
• Central composite design
• Workability
• Compressive strength