Acta Crystallographica Section E (Jun 2012)

3-Ethenyl-1-(4-methylphenylsulfonyl)-1H-indole

  • Julio Zukerman-Schpector,
  • Glaudeston D. Wulf,
  • Hélio A. Stefani,
  • Stanley N. S. Vasconcelos,
  • Seik Weng Ng,
  • Edward R. T. Tiekink

DOI
https://doi.org/10.1107/S1600536812021526
Journal volume & issue
Vol. 68, no. 6
pp. o1829 – o1830

Abstract

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Two independent but very similar molecules comprise the asymmetric unit of the title compound, C17H15NO2S. The molecules have L-shapes with the dihedral angles between the fused-ring system (r.m.s. deviations = 0.036 and 0.019 Å, respectively) and the benzene ring being almost the same, i.e. 82.98 (12) and 84.46 (13)°, respectively. The terminal ethenyl group is almost coplanar with the ring to which it is connected [C—C—C—C torsion angles = −173.7 (4) and −171.7 (4)°, respectively]. Supramolecular arrays parallel to (-124) stabilized by C—H...O and C—H...π interactions feature in the crystal packing.