Study on the Properties and Hydration Mechanism of Calcium Carbide Residue-Based Low-Carbon Cementitious Materials

Abstract

Alkali-activated cementitious materials, as an environmentally friendly cementitious material, can effectively reduce carbon emissions and improve the utilisation of solid wastes. However, traditional strong alkali activators have limitations such as high carbon emissions and poor safety. In order to overcome the defects of traditional strong alkaline activators and realise the high value-added use of calcium carbide residue (CCR), this paper adopts CCR as an alkaline activator to activate granulated blast furnace slag (GBFS)-steel slag (SS) cementitious systems for the preparation of alkaline-activated cementitious materials. The effects of CCR content and SS content on the compressive strength and working performance of CCR-GBFS-SS cementitious systems are analysed, along with the hydration process of CCR-GBFS-SS cementitious systems and the mechanism of action through the hydration products, their chemical structure and their microscopic morphology. The research results show that CCR-GBFS-SS cementitious systems have a 28-day compressive strength of 41.5 MPa and they can be controlled by the setting time; however, the flow performance is poor. The SS content can be increased to improve the flow performance; however, this will reduce the compressive strength. In CCR-GBFS-SS cementitious systems, CCR is the main driving force of hydration reactions, GBFS mainly provides active silica and aluminium and the amorphous C-(A)-S-H gel and ettringite formed by the synergistic action of multiple solid wastes are the main sources of compressive strength. With the extension of the curing time, the amount of hydration products in the cementitious systems gradually increases and the matrix of the cementitious systems gradually becomes denser. This study will provide a reference for the consumption of low-value solid waste such as CCR and the preparation of low-carbon cementitious materials from multi-component solid wastes.

Keywords

• calcium carbide residue
• granulated blast furnace slag–steel slag cementitious systems
• compressive strength
• workability
• hydration process