Nature Communications (Jun 2021)

Electrochemical activation of C–H by electron-deficient W2C nanocrystals for simultaneous alkoxylation and hydrogen evolution

  • Xiu Lin,
  • Shi-Nan Zhang,
  • Dong Xu,
  • Jun-Jun Zhang,
  • Yun-Xiao Lin,
  • Guang-Yao Zhai,
  • Hui Su,
  • Zhong-Hua Xue,
  • Xi Liu,
  • Markus Antonietti,
  • Jie-Sheng Chen,
  • Xin-Hao Li

DOI
https://doi.org/10.1038/s41467-021-24203-8
Journal volume & issue
Vol. 12, no. 1
pp. 1 – 9

Abstract

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Designing electrode materials for mild and additive-free activation of C–H bonds is of great challenge. The authors report the application of electron-deficient W2C nanocrystal electrodes to boost the dissociation of C-H bonds toward the efficient alkoxylation and hydrogen evolution reactions.