Microwave plasma torch mass spectrometry for some rare earth elements

Abstract

Rare earth elements (REEs) have been widely applied in modern industry and material science due to their special chemical properties and luminescence properties, but their environment pollution problem has also attracted attention. How to trace and control impact of REEs on environment and develop highly sensitive methods for REEs analysis have practical significance. Microwave plasma torch (MPT) is a kind of simple, low power consumption (∼200 W) and easily operated plasma generators. When it was coupled with varied mass spectrometers as ion source of mass spectrometry (MS), i.e. MPT-MS can use for the analysis of metal elements in aqueous with the remarkable advantage of only minimal or even no simple pretreatment, and can meet comprehensive requirements of environmental control and water quality monitoring. MPT-MS have also an ability to carry out online real-time monitoring and analysis of water environment. Compared with the traditional ICP-MS, it can obtain more effective information and has higher sensitivity (the detection limit is at sub-ppb level). This paper reviews common methods and research progress of REEs analysis in recent years. Practical applications and advantages of MPT in the analysis of REEs are briefly summarized. Specifically, this paper introduces some work recently done in our group on analysis of REEs by the MPT, including analysis of metal elements distribution in water samples in local Poyang Lake, and general rules of formation and behavior of complex metal ions in the MPT plasma are also proposed afterwards. Through the practically dealing with the Poyang Lake case by the MPT, hopefully this would interest more academia into this area so as to speed up development of the MPT itself.

Keywords

• Microwave plasma torch
• Ambient Mass Spectrometry
• Fieldable ion source
• Rare earth elements