Acta Crystallographica Section E (Nov 2010)
Chloridodimethyl(thiosemicarbazide)tin(IV) chloride
Abstract
In the title salt, [Sn(CH3)2Cl(CH4N3S)]Cl, the SnIV atom is five-coordinated in a distorted trigonal-bipyramidal geometry with two methyl groups and one S atom in the equatorial plane, and one N atom and one Cl atom occupying the apical positions. In the crystal, molecules are linked by intermolecular N—H...S hydrogen bonds with set graph-motif C(4) along [010]. N—H... Cl hydrogen bonds with graph-set motif D(2) and D33(10) link cations and anions.