Crystal structure of 2-cyano-1-methylpyridinium perchlorate

Abstract

The asymmetric unit of the title salt, C7H7N2+·ClO4−, comprises two independent formula units. The solid-state structure comprises corrugated layers of cations and of anions, approximately parallel to (010). The supramolecular layers are stabilized and connected by C—H...O hydrogen bonding to consolidate a three-dimensional architecture. A close pyridinium–perchlorate N...O contact [2.867 (5) Å] is noted. The crystal was refined as an inversion twin.

Keywords

• crystal structure
• salt
• pyridinium
• perchlorate
• hydrogen bonding