Synthesis and crystal structure of a heterobimetallic cadmium–sodium complex of 1,3,5-triazine-2,4,6-trione, [CdNa2(C3H2N3O3)4(H2O)8]

Abstract

Heterobimetallic crystals of a cadmium–sodium complex of 1,3,5-triazine-2,4,6-trione, namely, μ-aqua-1:2κ2O:O-heptaaqua-1κ3O,2κ2O,3κ2O-bis(μ-4,6-dioxo-1,4,5,6-tetrahydro-1,3,5-triazin-2-olato)-1:2κ2O2:N1;2:3κ2N1:O2-bis(4,6-dioxo-1,4,5,6-tetrahydro-1,3,5-triazin-2-olato)-1κO2,3κO2-2-cadmium-1,3-disodium, [CdNa2(C3H2N3O3)4(H2O)8], were grown by the single gel diffusion technique. The asymmetric unit of the title compound comprises four 1,3,5-triazine-2,4,6-trione ligands, two sodium atoms and one cadmium atom. Of the four ligands, two are monodentately coordinated to two Na atoms. The third ligand is coordinated bidentately to one Na and the Cd atom and the fourth is also coordinated bidentately to the Cd atom and the other Na atom. All the metal atoms are six-coordinate with a distorted octahedral geometry. The water molecules bridge the Na atoms, constructing coordination polymer chains along the a axis and hence are linked by two Cd and one Na coordinations through the cyanuric acid ligands present in the coordination polymer chains, generating a two-dimensional coordination polymer in the (110) plane. The polymer formation is further assisted by means of many intermolecular and intramolecular N—H...O, O—H...O and O–H...N hydrogen bonds between the water molecules and the ligands.

Keywords

• crystal structure
• heterobimetallic cadmium–sodium complex
• gel growth
• 1,3,5 triazine-2,4,6-trione
• two-dimensional coordination polymer