Acta Crystallographica Section E (Jul 2011)

Poly[aquabis[μ2-2-(pyridin-4-ylsulfanyl)acetato]zinc]

  • Zhi-Chao Wang,
  • Bo Ding,
  • Xiu-Guang Wang,
  • Xiao-Jun Zhao

DOI
https://doi.org/10.1107/S1600536811024512
Journal volume & issue
Vol. 67, no. 7
pp. m995 – m995

Abstract

Read online

The crystal structure of the title complex, [Zn(C7H6NO2S)2(H2O)]n, consists of extended layers parallel to (001) with 2-(pyridin-4-ylsulfanyl)acetate ligands bridging the ZnII atoms. The ZnII atom shows a distorted pentagonal–bipyramidal coordination environment. The ZnII and one O atom are situated on a crystallographic twofold rotation axis. In the crystal, intralayer O—H...O hydrogen-bond interactions help to consolidate the coordination layer.