[μ-N,N′-Bis(diphenylphosphinomethyl)benzene-1,4-diamine-κ2P:P′]bis[(2,2′-bipyridine-κ2N,N′)silver(I)] bis(perchlorate) acetone disolvate

Abstract

The title complex, [Ag2(C10H8N2)2(C32H30N2P2)](ClO4)2·2CH3COCH3, is a centrosymmetric dimer with pairs of AgI atoms bridged by N,N′-bis(diphenylphosphinomethyl)benzene-1,4-diamine ligands. In addition, each AgI atom is coordinated by one chelating 2,2′-bipyridine ligand, giving a distorted trigonal coordination environment.