SYSTEMATIC COMPARISON OF THE SOLUBILITY AND SUPERSOLUBILITY ON THE BASE OF THE SALT DIMENSIONAL FACTORS

Abstract

A comparison of the solubility line and the metastability boundary in aqueous solutions have been carried out on the basis of the salt dimensional factors. It is shown that these solution parameters and other ones are changed non-monotonically due to the ionic radii increasing for iso- valence salt groups. It is observed the salt taxonomy on the characteristic subgroups of ideal and non- ideal electrolytes.

Keywords

• ion dimension
• mechanism of the nano-stage nucleation
• solution supercooling
• dimensional dependence of the salt solubility and supersolubility