Acta Crystallographica Section E (Jan 2011)

2-[(E)-(4-Methylphenyl)iminomethyl]-6-(morpholin-4-ylmethyl)phenol

  • Mahdi Aberi,
  • Seid Ali Torabi Badrabady,
  • Hashem Sharghi,
  • Aliasghar Jarrahpour,
  • Sevim Türktekin,
  • Mehmet Akkurt,
  • Orhan Büyükgüngör

DOI
https://doi.org/10.1107/S1600536810052311
Journal volume & issue
Vol. 67, no. 1
pp. o147 – o148

Abstract

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In the title compound, C19H22N2O2, the morpholine ring adopts an almost perfect normal chair conformation with puckering parameters QT, θ and ϕ of 0.5642 (18) Å, 177.32 (17) and ϕ = 10 (4)°, respectively. The two benzene rings make a dihedral angle of 42.67 (8)° with each other. An intramolecular O—H...N hydrogen bond helps to stabilize the molecular conformation. Aromatic C—H...π interactions and π–π stacking interactions [centroid–centroid distance = 3.6155 (15) Å] between the benzene rings contribute to the stabilization of the crystal structure.