Heliyon (May 2024)
Optimization of cobalt-based MOFs for super-capacitor electrode materials of new energy vehicle
Abstract
Super-capacitors (SCs), as new energy conversion storage elements, have attracted much attention, but there is still a research gap in the design of electrode materials. In this study, the optimization scheme of Metal-Organic Frameworks (MOFs) and cobalt-based MOF composites as electrode materials for SCs in new energy vehicles is explored, and a series of experiments are conducted to evaluate their performance. Scanning Electron Microscope (SEM) images reveal that the cobalt-based MOF composites have a surface morphology of particles with uniform distribution. The electrochemical performance test results show that the specific capacitance of the cobalt-based MOF composites is much higher than the sum of the two individual electrode materials and presents a remarkable increase with the scanning rate. Additionally, in the constant current charge-discharge test, cobalt-based MOF composites exhibit the longest charge-discharge time and good symmetry. Electrolyte particle contact tests for samples at different preparation temperatures display that high-temperature samples have better structural stability and electrolyte ion contact. In Cyclic Voltammetry (CV) and Galvanostatic Charge Discharge (GCD) tests, the 250 °C sample demonstrates the best electrochemical properties and the highest specific capacitance (269 F/g). Moreover, as the current density increases, the specific capacitance of the 600 °C sample decreases at a lower rate, showing stronger stability. However, the use of cobalt-based MOF materials may pose environmental and safety risks, such as the environmental impact of cobalt resource mining, instability under high-temperature conditions, and the possible production of hazardous substances. Therefore, these factors need to be fully considered when designing and using SCs to ensure the environmental friendliness and safety of cobalt-based MOFs. These results provide an important reference for selecting and optimizing electrode materials for SCs in new energy vehicles. Furthermore, this study offers research suggestions for improving new energy materials, filling the research gaps in related fields, and supporting the further development of SC technology.
