Gels (Dec 2022)
Preparation Method and Performance Evaluation of a Gel Based on AM/AMPS Copolymer
Abstract
Polymer gels have been widely used in high water cut oilfields for profile control and water plugging. It is urgent to develop a gel suitable for the Tahe Oilfield (Temperature: 130 °C, salinity: 2.2 × 105 mg/L) in China. A stable gel was prepared by using an acrylamide (AM)/2-acrylamide-2-methyl propanesulfonic acid (AMPS) copolymer crosslinked with urotropin (HMTA), hydroquinone (HQ), thiourea and Nano-SiO2. This paper covers a step-by-step process for designing gels based on experience with preparing gels. A wide range of combinations between polymers and crosslinking agents with and without stabilizers were investigated, and the results indicated that there is an optimal value of AMPS content of AM/AMPS copolymers in the preparation of gels. Increasing the mass fraction of copolymer and using stabilizer enhanced the performance of gel, but an excessive amount of crosslinking agent was not conducive to the stability of gel. The work optimized the formula of plugging agent suitable for the high temperature and high salt (HTHS) condition in the Tahe Oilfield. The gelling solution had a long gelation time of 20 h. The gel had high strength (Sydansk’s gel-strength code of “G”) with storage modulus of 12.9 Pa and could be stable for half a year at 130 °C and 2.2 × 105 mg/L of salinity. The plate model that could be heated and pressurized was used to simulate the oil flooding and profile modification under the condition of the Tahe Oilfield for the first time. The experiment results showed that the oil recovery could be increased by 13.22% by subsequent water flooding under heterogeneous formation condition. Therefore, it was fully confirmed that the plugging performance of AM/AMPS phenolic gel prepared in the work was excellent. The information provided in the study could be used as a reference for the design and evaluation of polymer gels in other HTHS reservoirs.
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