An Updated Review for Performance Enhancement of Solar Cells by Spectral Modification

Abstract

Photovoltaic technology has become one of the major renewable ways to generate electric power. However, the mismatch between the incident solar spectrum and photo-electric response efficiency of solar cells severely constrains their performance. Hence, spectral modification technologies, e.g., up-conversion (UC), down-conversion (DC), and luminescent down-shifting (LDS) technologies have been applied widely in the photovoltaic field to reform the incident spectrum to match the best response band possible. In this paper, we review the latest developments of the three technologies above in terms of material selection, optical characteristics, and photovoltaic performance. It is found that the three most popular materials for conversion are NaYF4: Er3+, Yb3+, and Yb3+. The excitation bands for the three technologies are 800–1550 nm, 250–488 nm, and 250–488 nm, respectively, while the emission bands are 523–669 nm, 520–1031 nm, and 490–1010 nm, respectively. Furthermore, issues hindering the development of spectral modification technologies are pointed out, e.g., low absorption efficiency, poor quantum conversion efficiency, and hurdles in commercialization. Finally, suggestions and solutions to address the above-mentioned issues are provided.

Keywords

• photovoltaic
• spectral modification
• up-conversion
• down-conversion
• luminescent down-shifting