Growth and Characterizations of Organic NLO Imidazolium L-Tartrate (IMLT) Single Crystal

Abstract

Good quality single crystals of organic imidazolium L-Tartrate (IMLT) are grown up from aqueous solution by slow solvent evaporation technique. Various structural parameters and monoclinic crystal structure have been confirmed using powder X-ray diffraction method. The presence of various functional groups has been identified by ATR-FTIR. UV-Vis-NIR spectroscopy has shown more than 60% of optical transparency with the lower UV cutoff at 245nm. The optical band gap value of the material is evaluated to be 4.8 eV. Other optical parameters such as refractive index, optical and electrical conductivity, Urbach energy, extinction coefficient, and optical and electrical susceptibility have been evaluated from transmission spectrum data. The above essential parameters manifest appropriate usage of IMLT as an NLO material. The thermogravimetric analysis indicates high thermal stability of material up to 214°C. Apart from that, the dielectric study at various temperatures confirms decrement of dielectric constant and dielectric loss at higher frequencies. The efficiency of Second Harmonic Generation (SHG) is found to be 3.5 times that of the KDP crystals. A range of analysis suggests suitability and potentiality of IMLT crystal for various optoelectronic applications.