TDAE Strategy in the Benzoxazolone Series: Synthesis and Reactivity of a New Benzoxazolinonic Anion

Aïda R. Nadji-Boukrouche; Omar Khoumeri; Thierry Terme; Messaoud Liacha; Patrice Vanelle

doi:10.3390/molecules20011262

Molecules (Jan 2015)

TDAE Strategy in the Benzoxazolone Series: Synthesis and Reactivity of a New Benzoxazolinonic Anion

Aïda R. Nadji-Boukrouche,
Omar Khoumeri,
Thierry Terme,
Messaoud Liacha,
Patrice Vanelle

Affiliations

Aïda R. Nadji-Boukrouche: Procédés, Université 8 mai 1945 Guelma, BP 401, Guelma 24000, Algeria
Omar Khoumeri: Aix-Marseille Université, CNRS, Institut de Chimie Radicalaire ICR, UMR 7273, Laboratoire de Pharmaco-Chimie Radicalaire, Marseille 13385, France
Thierry Terme: Aix-Marseille Université, CNRS, Institut de Chimie Radicalaire ICR, UMR 7273, Laboratoire de Pharmaco-Chimie Radicalaire, Marseille 13385, France
Messaoud Liacha: Laboratoire de Synthèse et de Biocatalyse Organique (LSBO), Faculté des Sciences, Université Badji Mokhtar-Annaba, BP 12 El-Hadjar, Annaba 23000, Algeria
Patrice Vanelle: Aix-Marseille Université, CNRS, Institut de Chimie Radicalaire ICR, UMR 7273, Laboratoire de Pharmaco-Chimie Radicalaire, Marseille 13385, France

DOI: https://doi.org/10.3390/molecules20011262
Journal volume & issue: Vol. 20, no. 1
pp. 1262 – 1276

Abstract

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We describe an original pathway to produce new 5-substituted 3-methyl-6-nitro-benzoxazolones by the reaction of aromatic carbonyl and α-carbonyl ester derivatives with a benzoxazolinonic anion formed exclusively via the TDAE strategy.

Published in Molecules

ISSN: 1420-3049 (Online)
Publisher: MDPI AG
Country of publisher: Switzerland
LCC subjects: Science: Chemistry: Organic chemistry
Website: http://www.mdpi.com/journal/molecules

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