Efficient Synthesis and Reaction Kinetics of Readily Water Soluble Esters Containing Sulfonic Groups

Krzysztof R. Idzik; Karsten Nödler; Friedrich Maier; Tobias Licha

doi:10.3390/molecules191221022

Molecules (Dec 2014)

Efficient Synthesis and Reaction Kinetics of Readily Water Soluble Esters Containing Sulfonic Groups

Krzysztof R. Idzik,
Karsten Nödler,
Friedrich Maier,
Tobias Licha

Affiliations

Krzysztof R. Idzik: Department Applied Geology, Geoscience Centre of the University of Göttingen, Goldschmidtstrasse 3, Göttingen 37077, Germany
Karsten Nödler: Department Applied Geology, Geoscience Centre of the University of Göttingen, Goldschmidtstrasse 3, Göttingen 37077, Germany
Friedrich Maier: Department Applied Geology, Geoscience Centre of the University of Göttingen, Goldschmidtstrasse 3, Göttingen 37077, Germany
Tobias Licha: Department Applied Geology, Geoscience Centre of the University of Göttingen, Goldschmidtstrasse 3, Göttingen 37077, Germany

DOI: https://doi.org/10.3390/molecules191221022
Journal volume & issue: Vol. 19, no. 12
pp. 21022 – 21033

Abstract

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A series of various readily water soluble esters were synthesized by a very efficient procedure. These compounds can be useful as thermosensitive tracers for studying the cooling progress in a low enthalpy georeservoir exploitable by double flash geothermal power plant systems. The kinetics of their hydrolysis was investigated. Acylation of primary alcohols or phenols was carried out by a method based on a single-phase solvent system consisting of ethyl acetate acting as an organic solvent and triethylamine acting as a catalyst. Products were characterized by 1H-NMR, and 13C-NMR.

Published in Molecules

ISSN: 1420-3049 (Online)
Publisher: MDPI AG
Country of publisher: Switzerland
LCC subjects: Science: Chemistry: Organic chemistry
Website: http://www.mdpi.com/journal/molecules

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