Iranian Journal of Chemistry & Chemical Engineering (Jun 2017)

BiFeO3 Magnetic Nanoparticles: A Novel, Efficient and Reusable Magnetic Catalyst for the Synthesis of Polyhydroquinoline Derivatives

  • Maryam Khashi,
  • Sadegh Allameh,
  • Safar Ali Beyramabadi,
  • Ali Morsali,
  • Elnaz Dastmalchian,
  • Azar Gharib

Journal volume & issue
Vol. 36, no. 3
pp. 45 – 52

Abstract

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Herein, it has been shown that the bismuth ferrite magnetic nanoparticles (BFO-MNPs) are new, efficient and recyclable catalysts for the synthesis of polyhydroquinoline derivatives by the Hantzsch reaction. The one-pot four-component cyclocondensation reaction of dimedone, aromatic aldehydes, ethyl acetoacetate and ammonium acetate was carried out under solvent-free conditions. The desired products were obtained in very short reaction times with high yields. The magnetic nanocatalyst was characterized by the X-Ray Diffraction (XRD) and FT-IR analysis. For the first time, the bismuth ferrite magnetic nanoparticles were used as a catalyst in the Hantzsch reaction. The catalyst was found to be reusable, which showed considerable catalytic activity after the third run.

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