2013–2014 Survey of Chars Using Raman Spectroscopy

Abstract

In late 2013, an open call for charcoal and biochar samples was distributed in an effort to compare a wide range of char samples by Raman spectroscopy. The samples contributed to this survey included: laboratory produced biochars, recent biochars produced in field conditions, and ancient char samples previously analysed by carbon dating. By using selected Raman measurements, the char samples could be ranked in terms of the degree of thermochemical alteration or extent of carbon nanostructural development. The Raman results for recently produced biomass chars were generally consistent with the conversion of amorphous carbon formed at lower temperatures into condensed, polyaromatic, and graphene-like carbon formed at higher temperatures. A number of parameters calculated from the Raman spectra could be used to estimate the effective heat treatment temperatures in the recently produced biochars. Other samples such as anthracite coal, tire pyrolysis carbon, and ancient chars departed from the trends observed in the recently produced biomass chars using this approach. In total, 45 samples were analysed by Raman spectroscopy for this survey. Ancient and buried char samples displayed higher intensities for features in the Raman spectra associated with amorphous carbon.

Keywords

• biochars
• charcoal
• char
• Raman spectroscopy