Influences of humic acid on the release of polybrominated diphenyl ethers from plastic waste in landfills under different environmental conditions

Abstract

Landfill-formed humic acid are an important substance in landfill leachate. The effect of landfill-formed humic acid in different environments (temperature and surfactant concentrations) on the release of chemicals from plastic waste remains unknown. In order to explore the pollution release rates of polybrominated diphenyl ethers (PBDEs) in different plastic waste, humic acid were used as the extractant to conduct leaching simulation tests to study the effects of time, temperature, and surfactant (sodium dodecyl benzene sulfonate (SDBS)) concentrations on the release of PBDEs in waste. This waste includes polypropylene random pipes (PPRP), polyethylene of raised temperature resistance pipes (PERTP), polyvinyl chloride pipes (PVCP), polypropylene plastic benches (PPB), polypropylene washing machines (PPWM), polystyrene television (PSTV), and flame-retardant acrylonitrile butadiene styrene (FRABS). The leaching amounts of PBDEs had significant linear growth over time. Among them, the leaching amount of PBDEs in daily plastics is lower than dismantling plastics. The rate of leaching of BDE-209 was greater than the other congeners, with a leaching amount of up to 93.10%. Different types of waste exhibited different changes with temperature and surfactants concentrations. Among all the waste types, the leaching amounts of PBDEs in PPRP and PERTP gradually increased with increasing temperature. Surfactants within a certain concentration range can promote the release of PBDEs. The purpose of the research is to explore the dissolution law of PBDEs of different plastic products and the same product in different environment, provides a theoretical basis for the management and risk control of landfills.

Keywords

• Landfill process
• Humic acid
• Polybrominated diphenyl ether
• Dismantling plastic
• Leaching characteristics