Molecules (Apr 2018)

Zeta Potential of Beta Zeolites: Influence of Structure, Acidity, pH, Temperature and Concentration

  • Xuan Liu,
  • Päivi Mäki-Arvela,
  • Atte Aho,
  • Zuzana Vajglova,
  • Vladimir M. Gun’ko,
  • Ivo Heinmaa,
  • Narendra Kumar,
  • Kari Eränen,
  • Tapio Salmi,
  • Dmitry Yu. Murzin

DOI
https://doi.org/10.3390/molecules23040946
Journal volume & issue
Vol. 23, no. 4
p. 946

Abstract

Read online

Measurements of the zeta potential of solid heterogeneous supports are important for preparation of metal supported catalysts and for shaping zeolites into extrudates. In the current work, different types of heterogeneous support materials such as SiO2, Al2O3, and a range of beta zeolites of different silica- to-alumina ratio were analysed. It was observed that parameters such as temperature, pH and acidity significantly affect the zeta potential. In several instances, depending on the materials’ acidity and microstructure, maxima in zeta potential were observed. The solid materials were thoroughly characterized using XRD, SEM, EDX, TEM, nitrogen physisorption, Al-NMR and FTIR with pyridine before zeta potential measurements.

Keywords