Removal of Acidic Organic Ionic Dyes from Water by Electrospinning a Polyacrylonitrile Composite MIL101(Fe)-NH<sub>2</sub> Nanofiber Membrane

Jiao Jia; Hao Wu; Le Xu; Fengchun Dong; Yongtang Jia; Xi Liu

doi:10.3390/molecules27062035

Molecules (Mar 2022)

Removal of Acidic Organic Ionic Dyes from Water by Electrospinning a Polyacrylonitrile Composite MIL101(Fe)-NH<sub>2</sub> Nanofiber Membrane

Jiao Jia,
Hao Wu,
Le Xu,
Fengchun Dong,
Yongtang Jia,
Xi Liu

Affiliations

Jiao Jia: Guangdong-Hong Kong Joint Laboratory for New Textile Materials, Guangdong Functional Fiber and Textile Engineering Technology Research Center, School of Textile Materials and Engineering, Wuyi University, Jiangmen 529020, China
Hao Wu: Guangdong-Hong Kong Joint Laboratory for New Textile Materials, Guangdong Functional Fiber and Textile Engineering Technology Research Center, School of Textile Materials and Engineering, Wuyi University, Jiangmen 529020, China
Le Xu: Guangdong-Hong Kong Joint Laboratory for New Textile Materials, Guangdong Functional Fiber and Textile Engineering Technology Research Center, School of Textile Materials and Engineering, Wuyi University, Jiangmen 529020, China
Fengchun Dong: Guangdong-Hong Kong Joint Laboratory for New Textile Materials, Guangdong Functional Fiber and Textile Engineering Technology Research Center, School of Textile Materials and Engineering, Wuyi University, Jiangmen 529020, China
Yongtang Jia: Guangdong-Hong Kong Joint Laboratory for New Textile Materials, Guangdong Functional Fiber and Textile Engineering Technology Research Center, School of Textile Materials and Engineering, Wuyi University, Jiangmen 529020, China
Xi Liu: Guangdong-Hong Kong Joint Laboratory for New Textile Materials, Guangdong Functional Fiber and Textile Engineering Technology Research Center, School of Textile Materials and Engineering, Wuyi University, Jiangmen 529020, China

DOI: https://doi.org/10.3390/molecules27062035
Journal volume & issue: Vol. 27, no. 6
p. 2035

Abstract

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A nanofiber metal–organic framework filter, a polyacrylonitrile (PAN) nanofiber membrane composite with an iron/2-amino-terephthalic acid-based metal–organic framework (MIL101(Fe)-NH2), was prepared by one-step electrospinning. MIL101(Fe)-NH2 was combined into the polymer nanofibers in situ. PAN-MIL101(Fe)-NH2 composite nanofiber membranes (NFMs) were prepared from a homogeneous spinning stock containing MIL101(Fe)-NH2 prebody fluid and PAN. Crystallization of MIL101(Fe)-NH2 and solidification of the polymer occurred simultaneously during electrospinning. The PAN-MIL101(Fe)-NH2 composite NFM showed that MIL101(Fe)-NH2 was uniformly distributed throughout the nanofiber and was used to adsorb and separate acidic organic ionic dyes from the aqueous solution. The results of Fourier transform infrared spectroscopy, energy-dispersive X-ray spectroscopy, and X-ray diffraction analysis showed that MIL101(Fe)-NH2 crystals were effectively bonded in the PAN nanofiber matrix, and the crystallinity of MIL101(Fe)-NH2 crystals remained good, while the distribution was uniform. Owing to the synergistic effect of PAN and the MIL101(Fe)-NH2 crystal, the PAN-MIL101(Fe)-NH2 composite NFM showed a fast adsorption rate for acidic ionic dyes. This study provides a reference for the rapid separation and purification of organic ionic dyes from wastewater.

Published in Molecules

ISSN: 1420-3049 (Online)
Publisher: MDPI AG
Country of publisher: Switzerland
LCC subjects: Science: Chemistry: Organic chemistry
Website: http://www.mdpi.com/journal/molecules

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