Generation of pyridyl coordinated organosilicon cation pool by oxidative Si-Si bond dissociation

Toshiki Nokami; Ryoji Soma; Yoshimasa Yamamoto; Toshiyuki Kamei; Kenichiro Itami; Jun-ichi Yoshida

doi:10.1186/1860-5397-3-7

Beilstein Journal of Organic Chemistry (Feb 2007)

Generation of pyridyl coordinated organosilicon cation pool by oxidative Si-Si bond dissociation

Toshiki Nokami,
Ryoji Soma,
Yoshimasa Yamamoto,
Toshiyuki Kamei,
Kenichiro Itami,
Jun-ichi Yoshida

Affiliations

Toshiki Nokami: Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Kyotodaigakukatsura, Nishikyo-ku, Kyoto, 615-8510, Japan
Ryoji Soma: Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Kyotodaigakukatsura, Nishikyo-ku, Kyoto, 615-8510, Japan
Yoshimasa Yamamoto: Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Kyotodaigakukatsura, Nishikyo-ku, Kyoto, 615-8510, Japan
Toshiyuki Kamei: Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Kyotodaigakukatsura, Nishikyo-ku, Kyoto, 615-8510, Japan
Kenichiro Itami: Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Kyotodaigakukatsura, Nishikyo-ku, Kyoto, 615-8510, Japan
Jun-ichi Yoshida: Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Kyotodaigakukatsura, Nishikyo-ku, Kyoto, 615-8510, Japan

DOI: https://doi.org/10.1186/1860-5397-3-7
Journal volume & issue: Vol. 3, no. 1
p. 7

Abstract

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An organosilicon cation stabilized by intramolecular pyridyl coordination was effectively generated and accumulated by oxidative Si-Si bond dissociation of the corresponding disilane using low temperature electrolysis, and was characterized by NMR and CSI-MS.

Published in Beilstein Journal of Organic Chemistry

ISSN: 1860-5397 (Online)
Publisher: Beilstein-Institut
Country of publisher: Germany
LCC subjects: Science: Chemistry: Organic chemistry
Website: http://www.beilstein-journals.org/bjoc

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