Investigation of the Characteristics of Catalysis Synergy during Co-Combustion for Coal Gasification Fine Slag with Bituminous Coal and Bamboo Residue

Abstract

As a kind of solid waste from coal chemical production, the disposal of coal gasification fine slag poses a certain threat to the environment and the human body. It is essential for gasification slag (GS) to realize rational utilization. GS contains fewer combustible materials, and the high heating value is only 9.31 MJ/Kg, which is difficult to burn in combustion devices solely. The co-combustion behavior of the tri-fuel blends, including bituminous coal (BC), gasification slag (GS), and bamboo residue (BR), was observed by a thermogravimetric analyzer. The TGA results showed that the combustibility increased owing to the addition of BC and BR, and the ignition and burnout temperatures were lower than those of GS alone. The combustion characteristics of the blended samples became worse with the increase in the proportion of GS. The co-combustion process was divided into two main steps with obvious interactions (synergistic and antagonistic). The synergistic effect was mainly attributed to the catalysis of the ash-forming metals reserved with the three raw fuels and the diffusion of oxygen in the rich pore channels of GS. The combustion reaction of blending samples was dominated by O1 and D3 models. The activation energy of the blending combustion decreased compared to the individual combustion of GS. The analysis of the results in this paper can provide some theoretical guidance for the resource utilization of fine slag.

Keywords

• coal gasification fine slag
• co-combustion
• catalytic interaction
• reaction kinetic