Acta Crystallographica Section E (Apr 2009)
(E)-N′-(4-Bromobenzylidene)-p-toluenesulfonohydrazide
Abstract
In the title compound, C14H13BrN2O2S, a novel sulfonamide derivative, intermolecular N—H...O and C—H...O hydrogen bonds link neighbouring molecules into different dimers along the b axis, generating R22(8) and R22(16) ring motifs. The dihedral angle between the benzene rings is 82.39 (13)°. The crystal structure is further stabilized by intermolecular π–π stacking interactions [centroid–centroid distances = 3.867 (2)–3.9548 (8) Å].