Sugarcane Peel Ash as a Sorbent for Methylene Blue

Abstract

Sugarcane peel waste (SPW) modified by combustion was used as a sorbent for methylene blue (MB) in aqueous medium under the influence of parameters such as pH of the medium, initial MB concentrations, contact time, SPW dosage, and temperature using batch experiments. The microstructure of the adsorbent was analyzed using Fourier infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX), and X-ray diffractometer (XRD). The quantity (mg/g) of adsorbed MB increased with increased contact time, rise in dye concentration, as well as the solution pH. Similarly, the temperature of the system improved the sorption effectiveness with maximum sorption capacity of 65.4 and 81.2% at 45 °C and 55 °C for USPW and MSPW, respectively. At an initial MB concentration of 100 mg/L, temperature of 45 °C and 55 °C, pH of 4, and reaction times of 80 and 60 min for unmodified sugarcane peel waste (USPW) and modified sugarcane peel waste (MSPW), respectively, optimal MB adsorption of 22.6 and 33.2 mg g-1, respectively, was achieved.

Keywords

• adsorbent
• ash
• cellulose
• biomass
• dye
• isotherms
• kinetics